Exploring Dicarboxylic Acid Interactions and Surface Chemistry Through X-ray Photoelectron Spectroscopy

Authors

  • Ghafoor Ahmad Collaborative Innovation Center of Chemical Science and Engineering, Key Laboratory for Green Chemical Technology of Ministry of Education and School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China.
  • Md Wazed Hossan Shehab School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China. c Department of Zoology, Minhaj University, Lahore 54000, Pakistan
  • Hosen Md Sajib School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China. c Department of Zoology, Minhaj University, Lahore 54000, Pakistan
  • Muhmmad Saleem Department of Zoology, Minhaj University, Lahore 54000, Pakistan
  • Md Atoar Hossan Siblu School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, P. R. China.
  • Tayyaba Munawar Department of Chemistry, University of Agriculture, Faisalabad 38040, Pakistan
  • Abu Musa Sarkar School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China. c Department of Zoology, Minhaj University, Lahore 54000, Pakistan
  • Hafiz Mahmood Ul Hasan Collaborative Innovation Center of Chemical Science and Engineering, Key Laboratory for Green Chemical Technology of Ministry of Education and School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China.

DOI:

https://doi.org/10.63278/mme.vi.1661

Keywords:

Dicarboxylic acids; X-ray photoelectron spectroscopy; Surface modification; Surface chemistry; Binding energy shifts.

Abstract

Dicarboxylic acids have become key players in designing functional surfaces, offering precise control over interactions in catalysis, materials science, and environmental applications. However, understanding their complex chemical states and surface behavior remains a challenge. Advanced X-ray photoelectron spectroscopy (XPS), known for its ability to identify elements and resolve chemical states, is now essential for studying these systems at the molecular level. This review explores recent advancements in cutting-edge XPS techniques, including synchrotron-based, angle-resolved, and ambient-pressure methods, to analyze surfaces modified with dicarboxylic acids. It highlights important findings on metal-ligand interactions, electrical conductivity, and degradation processes in systems like metal-organic frameworks, hydrogels, composite adsorbents, and single-atom catalysts. The discussion focuses on how the shifts in binding energy, peak analysis, and oxidation state mapping connect to functional properties such as adsorption capacity, catalytic performance, and interfacial role. Additionally, the review addresses ongoing challenges, such as beam-induced damage and reactivity under operational conditions, suggesting the integration of operando and multi-modal methods as a way forward. By emphasizing the role of XPS, this review establishes it as a cornerstone technique for unraveling dicarboxylic acid driven surface chemistry, paving the way for the rational design of sustainable and multifunctional materials.

Downloads

Published

2025-05-07

How to Cite

Ahmad , Ghafoor, Md Wazed Hossan Shehab, Hosen Md Sajib, Muhmmad Saleem, Md Atoar Hossan Siblu, Tayyaba Munawar, Abu Musa Sarkar, and Hafiz Mahmood Ul Hasan. 2025. “Exploring Dicarboxylic Acid Interactions and Surface Chemistry Through X-Ray Photoelectron Spectroscopy”. Metallurgical and Materials Engineering, May, 878-93. https://doi.org/10.63278/mme.vi.1661.

Issue

Vol. 31 No. 5 (2025)

Section

Research

License

Copyright (c) 2025 Ghafoor Ahmad , Md Wazed Hossan Shehab, Hosen Md Sajib , Muhmmad Saleem , Md Atoar Hossan Siblu, Tayyaba Munawar, Abu Musa Sarkar , Hafiz Mahmood Ul Hasan

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors who publish with this journal agree to the following terms:

  • Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
  • Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
  • Authors are permitted and encouraged to post their published articles online (e.g., in institutional repositories or on their website, social networks like ResearchGate or Academia), as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).

 

Creative Commons License
Except where otherwise noted, the content on this site is licensed under a Creative Commons Attribution 4.0 International License.