The Inhibitive effect of ethanolamine on corrosion behavior of aluminium in NaCl solution saturated with CO2
Keywords: aluminium, corrosion inhibitor, linear sweep voltametry, electrochemical impedance spectroscopy, Frumikin adsorption isotherm, scanning electron microscopy
AbstractIn this study, the inhibitive effect of ethanolamine on corrosion behavior of aluminium was investigated in 3 wt. % NaCl solution, saturated with CO2. All the experiments were carried out at 20°C. Ethanolamine was added at different concentrations between 1 mM and 8 mM. In order to determine the corrosion inhibition efficiency of investigated inhibitor and the optimal concentration of inhibitor that provides the lowest corrosion of aluminium, the open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), linear sweep voltametry (LSV) measurements, weight loss measurements as well as scanning electron microscopy technique (SEM) were performed. The electrochemical study and weight loss measurements indicated that the minimum corrosion rate and maximum inhibition efficiency was detected for concentration of 5 mM of ethanolamine, as well as the ethanolamine did not change the mechanism of aluminium dissolution. The adsorption of ethanolamine was found to obey Frumkin adsorption isotherm at concentrations up to 5 mM, but further increase in concentration was found to deviate from Frumkin adsorption isotherm. The calculated value for interaction parameter a indicates attractive lateral interactions in the adsorbed inhibitor layer. The obtained value of standard free energy of adsorption, ∆Gads θ , confirms that the adsorption process is favorable, spontaneous physisorption process.
Articles - archived
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their published articles online (e.g., in institutional repositories or on their website, social networks like ResearchGate or Academia), as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).
Except where otherwise noted, the content on this site is licensed under a Creative Commons Attribution 4.0 International License.